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Soda Bottle VolcanoAn Eruption Begins
(PDF version)
Overview: Examine how gases provide the energy to create explosive
volcanic eruptions by making comparisons to gases in a soda bottle and
by conducting a carefully controlled "eruption" of baking soda/vinegar
or soda water.
Objectives: Students will
- Understand the important role of gases in providing energy for explosive
volcanic eruptions
- Understand how pressure affects gases
- Learn how gases influence the texture and appearance of volcanic
rocks
Essential Academic Learning Requirements met by this activity:
- Communication: 1.1, 1.2, 3.2, 3.3
- Math: 1.1, 1.2, 1.3, 2.3, 4.2
- Reading: 1.1, 1.2, 1.3, 2.1, 2.2, 3.2
- Science: 1.1, 1.2, 1.3, 3.2
Materials needed:
- Human MoleculesStudying the Role of Gas Bubbles in an Explosive
Eruption"
- Graphic "The Role of
Gas Bubbles in an Eruption"
- Teacher PageNarrative "What Starts
an Eruption?"
Making Your Own Volcanic EruptionOption 2
- Graphic "Soda Bottle Volcano"
- 20 oz clear plastic soda bottle for each student
- Permanent ink marker pen
- 1 box baking soda
- 2 gallons vinegar
- 1 box tissue
- Spoon
- Paper towels
- Tarp or other plastic floor covering (optional)
Timeframe: 40 minutes
- Human MoleculesStudying the Role of Gas Bubbles in an Explosive
Eruption
(15 minutes)
- Making Your Own Volcanic EruptionOption 1 or Option 2 (25 minutes)
Grade Level: 5-8
Setting: outdoors or uncarpeted classroom with a tarp or plastic
floor covering
Materials: Vocabulary: conduit, magma, magma chamber, exsolution,
fumaroles, pumice, scoria, throat, volcanic ash,
Skills: demonstrating, inferring, observing, predicting
Benchmarks:
Science 1 - The student understands and uses scientific concepts
and principles.
- 1.1 Use properties to identify, describe, and categorize substances,
materials, and objects, and use characteristics to categorize living
things; Classify rocks and soils into groups based on their chemical
and physical properties; describe the processes by which rocks and soils
are formed
Teacher Background:
WaterThe Surprisingly Essential Ingredient in Explosive Volcanic
Eruptions
Hot magma and water vapor seem incompatible. Yet, water vapor (H2O),
carbon dioxide (CO2), sulfur dioxide (SO2), and lesser amounts of rarer
gases take up as much as ten percent of the magma (by weight) that lies
beneath some Cascade volcanoes. These gases are important because their
expansion provides the energy that blasts magma to Earth's surface during
an explosive volcanic eruption.
About 80 kilometers (50 miles) below the Earth's surface, water sweats
off the subducted oceanic plate and promotes the formation of magma,
which then rises into the Earth's crust. Water vapor and other gases,
elements and minerals coexist as a mixture of molten or partially molten
magma having a texture similar to hot oatmeal.
A Magma Chamber is Like a Pot of Dessert Pudding
Imagine magma as home-cooked pudding bubbling in a pot topped by a tight
lid. Some of the ingredients in the pot combine as they cool; this is
similar to the process of elements combining to form minerals. During
this process, tiny bubbles of gas separate from their more solid surrounding
neighbors. Since gases are lighter, they rise to the top of the pudding
(or magma). As gases separate progressively from the pudding, bubbles
rise, expand, and form a gas-rich layer at the top of the pot (or magma
chamber).
The Pot Boils Over
The pressure of rising gases eventually forces the pot lid to vibrate.
Puffs of steam break out between the pot and lid in the same way that
volcanic gases escape the top of a magma chamber through cracks and openings
in surrounding rocks.
The upward pressure of gases eventually exceeds the downward pressure
exerted by the lid, and the pudding and gases pour over the side of the
pot and onto the stovetop. This is the same concept as lava escaping across
the slopes of an erupting volcano. Some of the pudding propels explosively
out of the pot and splatters everywhere, similar to magma erupting from
a volcano as rock fragments or ash.
Gas Bubbles Determine the Texture of Volcanic Rock
During an explosive volcanic eruption, gases escape into the atmosphere;
however, some become trapped in the quickly cooling magma. The erupted
magma, in the form of ash and lava, may contain bubble holes from the
former presence of gases. The resulting rocks appear similar to foam from
a bottle of soda. These rocks are called pumice and scoria.
Sometimes the gas-rich magma erupts so explosively that it breaks into
tiny fragments known as volcanic ash.
How the Soda Bottle Experiment Is Like a Volcano
The wide body and narrow neck of a soda bottle roughly resemble the shape
of a magma chamber and the conduit or throat within a volcano.
The pressurized soda water represents gas-rich magma that is under pressure
from overlying rocks. Carbonated beverages get their fizz from the gas
carbon dioxide. When the bottle is capped, carbon dioxide dissolves within
the soda from the pressure exerted on it. It also occupies the void between
the surface of the liquid and the cap. Shaking the bottle adds energy
and causes gas in the soda water to separate, forming tiny bubbles throughout
the liquid. Formation of the bubbles creates pressure inside the bottle.
Quickly removing the cap releases this pressure, and the bubbles immediately
expand. Forced up the narrow neck, the fluid and bubbles burst from the
high-pressure environment of the bottle to the lower pressure of the atmosphere.
Bubbles of water vapor and other gases within magma undergo a similar
progression. They are initially dissolved in magma, then depressurization
in the magma chamber frees the bubbles from the magma in a process called
exsolution. The bubbles rise to the top of the magma chamber. Pressure
from the gas bubbles propels both the magma and gas up the conduit. The
gas bubbles now rapidly expand to thousands of times their original volume
when escaping up the conduit to the top of the erupting volcano.
How the Vinegar and Baking Soda Eruption is Unlike a Volcano
Combining baking soda and vinegar causes a chemical reaction that quickly
produces carbon dioxide bubbles:
CH3COOH (Vinegar)+ NaHCO3 (Baking Soda) --> CH3COONa
+ H2O (Water) + CO2 (Carbon
Dioxide Gas)
This demonstration differs from the processes within real volcanoes,
because the gases that cause explosive eruptions do not result from sudden
chemical reactions. In the soda water and baking soda/vinegar experiments,
carbon dioxide acts as the main gas driving the explosion. In most volcanic
eruptions, water is the principal gas driving an explosive eruption and
not carbon dioxide.
Procedure:
Human MoleculesStudying the Role of Gas Bubbles in an Explosive
Eruption
Explore how gas molecules respond to pressure using an illustration and
classroom demonstration.
- Demonstrate how gas reacts to different pressure conditions. Divide
the class into two groups. One group will act as "rock walls"
and the other group will act as "gas molecules." The gas molecules
should always be in random motion.
- Instruct the "rock walls" to form a tight circle around
five of the "gas molecules." Further instruct students (walls)
not to change size of circle once formed.
- Ask the five students (gas molecules) in the center of the circle
to move randomly from one side of the "rock walls" to the
other. They should have a difficult time doing this in such a tight
space.
- Add one student at a time from the "gas molecules" group
to the inside of the circle until there are no more students (gas molecules)
left. Students should have a hard time squeezing into the circle if
the "rock walls" circle has not changed its size.
- Tell everyone to "Freeze."
- Explain to the students that they have just demonstrated what happens
in a magma chamber. Gases rise out of the magma and accumulate at the
top of the chamber. As more gases accumulate, the pressure increases.
Eventually the pressure of the gas exceeds the pressure of surrounding
rock, so the gases must escape up the magma conduit.
- Instruct the "rock walls" to enlarge the circle while the
"gas molecules" remain in place.
- Tell the "gas molecules" to mingle so that they move throughout
the entire space. This is what happens when pressure is decreased; gases
expand to fill up space.
- Instruct two people in the "rock wall" to open a hole in
the circle. This allows the "gas molecules" to escape rapidly,
as in a volcanic eruption.
Making Your Own Volcanic Eruption
Examine the role of gas in explosive volcanic eruptions by using a baking
soda/vinegar mixture in a bottle. This activity can be done as a demonstration
or in small student groups.
Teacher Tips: This activity can be messy, so do the experiment outside
or in an easy-to-clean area.
Vinegar and Baking Soda Eruption
- Explain to students that they will be making baking soda/vinegar volcanoes.
The baking soda reacts with vinegar to form carbon dioxide gas. Carbon
dioxide, sulfur dioxide, and water vapor are common volcanic gases.
Gases building up in the magma chamber provide the main trigger for
volcanic eruptions.
- Divide the class into groups of three or four.
- Give each group an empty 20 ounce soda bottle. Using the "Soda
Bottle Volcano" graphic as a model, have students draw a volcano
on the empty soda bottle showing the magma conduit (throat), magma chamber,
and surrounding rocks. Draw circles to illustrate bubbles that enlarge
as they rise because of reduction of pressure.
- Preferably in an outdoor setting, instruct students to prepare their
makeshift volcano by pouring vinegar into the bottle to a depth of about
5 cm (two inches).
- Each group should spoon one teaspoon of baking soda onto a thin piece
of tissue. Gather the sides of the tissue and twist together to form
a small bundle. Students SHOULD NOT push the baking soda bundle into
the bottle until instructed to do so.
- Before students activate the chemical reaction, inform them to make
some observation during the experiment. Each group should look, listen,
and feel for an increase in pressure within the bottle. They should
watch the gas bubbles and note any increase or decrease in size. Additionally,
they should keep an eye on the volume of gas bubbles produced during
the remainder of the experiment.
- Keeping the bottle pointed AWAY from viewers, students push the baking
soda bundle into the bottle of vinegar. They should immediately place
a hand over the top of the bottle and try not to let any gas escape.
They should feel the pressure build and hear the escaping gases make
hissing sounds similar to what you would hear near a real volcanic vent.
- Instruct students to shake the bottle for 10-20 seconds with their
hand firmly over the opening of the bottle. The gases inside the bottle
will dramatically expand and propel a foamy froth into the air and down
the sides of the bottle.
- How did the students' results compare to that of a real volcanic eruption?
Did the pressure increase? How do they know? How was covering the top
of the soda bottle similar to a closed magma conduit? What happened
to the size and quantity of the gas bubbles?
Adaptations
- Ask students to use different shaped containers that represent the
magma chamber and conduit of a volcano. How does shape affect the eruption
results?
- For younger students, direct them to draw lines on a piece of paper
that divide it into six sections. Ask students to draw a before, during,
and after experiment picture in squares 1, 2, and 3. Instruct students
to draw pictures in squares 4, 5, and 6, of what a volcano would look
like if it behaved like the experiment represented in squares 1, 2,
and 3 respectively.
Extensions
- Instruct students to make a four-page book that illustrates gas bubbles
increasing in size as the magma rises in the Earth and ends with a volcano
erupting.
- Search for the link between volcanic gases and acid lakes. Ask students
to use the Internet to research this topic. Some examples of acid lakes
include Lake Nyos, Cameroon, Kawa Ijen, Indonesia, and Santa Ana, El
Salvador.
- Direct students to explore Internet-based computer programs that simulate
volcanic eruptions. Note the list of selected computer programs in Internet
Resources.
Assessment:
Look for evidence of students' understanding of the following concepts:
that magma contains gases under great pressure; that gases provide the
energy for volcanic eruptions; that gases influence the texture and appearance
of volcanic rocks. Look for student's recognition that of the differences
between the baking soda and vinegar eruption which is based on chemical
reactions, and an actual volcanic eruption, which is based solely upon
pressure release.
What Starts an Eruption?
Narrative
Gases, such as water vapor, CO2, SO2, and other rarer gases, are the
driving forces that power explosive volcanic eruptions. However, gases
are not the only players in a volcanic eruption. The size and explosiveness
of an eruption are also controlled by the amount of magma in the magma
chamber, the magma's mineral composition, and the pressure change in the
narrow conduit that leads to Earth's surface.
Magma
Deep below the surface of the earth, the subducting plate's temperature
increases. Water rises out of the sinking slab, migrates into the surrounding
hotter mantle rock, and initiates melting. The molten rock is called magma.
Pressure
Pressure increases progressively with depth below Earth's surface at
a rate of 250 bars per kilometer (400 bars per mile). At sea level, we
feel approximately one bar (fourteen pounds per square inch) of pressure
from Earth's atmosphere. The pressure from the overlying rock can be 30,000
bars (440,000 pounds per square inch) or more! Steam and other gases dissolve
into the magma because of the extreme pressure exerted by overlying and
surrounding rocks.
Magma Chamber
The magma chamber is a zone of molten and partially molten rock that
exists beneath a volcano. The top of the magma chamber at Mount Rainier
is about eight kilometers (five miles) below the Earth's surface and is
only a few kilometers wide. As gas bubbles accumulate, the upward pressure
increases, forcing cracks in the rocks to widen.
Magma Conduit
With the accumulation and rise of bubbles through the magma chamber,
the pressure increases and will eventually become great enough to break
through overlying roof rocks, creating a conduit to the surface. Magma
escapes through the "super highway" of the volcano, known as
the magma conduit or throat. This long, narrow opening leads from the
top of the magma chamber to the Earth's surface. The throat of Mount Rainier
is only ten to fifteen meters (33 to 50 feet) wide and is currently filled
with solid rock.
As gas bubbles rush up the magma conduit, the pressure declines, causing
the bubbles to expand rapidly. They can expand to thousands of times their
original size! The rapid expansion of gas bubbles propels the magma and
gas up the conduit. Within minutes, the volcano erupts, explosively spewing
hot lava and tephra into the air. If the magma is "runny enough,"
the gas bubbles escape easily; and instead of exploding, magma pours down
the flanks of volcano as a lava flow.
Vents and Fumaroles
Cracks and fractures in the rock can allow gases to escape from the magma.
If enough gas escapes, the character of the eruption will be changed from
explosive to non-explosive.
References:
Decker, R. and Decker, B., 1998, Volcanoes: W.H. Freeman and Company,
New York, 321 pages.
Francis, P., and Oppenheimer, C., 2003: Volcanoes: Oxford University
Press, 536 pages.
VanCleve, Janice, 1994, VolcanoesMind-boggling experiments you
can turn into science fair projects: John Wiley and Sons, New York,
89 p.
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